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Discrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array data

dc.citation.titleJournal of the Brazilian Chemical Societyen
dc.citation.volume26(11)
dc.creatorAfonso, Sabrina
dc.creatorPisano, Pablo Luis
dc.creatorSilva, Fabiano
dc.creatorScaminio, Ieda
dc.creatorOlivieri, Alejandro César
dc.date.accessioned2019-02-08T19:44:22Z
dc.date.available2019-02-08T19:44:22Z
dc.date.issued2015-11
dc.descriptionSpecies of the Annonaceae family are used in traditional medicine, and several antitumor acetogenins have been isolated from the leaves of Annona muricata and Rollinia mucosa. Leaves samples (self-shaded and sun-exposed) of these species were collected during winter and summer seasons. Extraction media were prepared from mixtures of five solvents according to a simplex centroid design. Plant extracts were analysed by injection into a high-performance liquid chromatography with diode array detection (HPLC-DAD) and evaluated after applying by multivariate curve resolution-alternating least-squares (MCR-ALS) and discriminant-unfolded partial least-squares (D-UPLS). The objective was to check whether the chemometric resolution of chromatographic profiles could help in the discrimination of samples according to taxonomic classification, sun exposition and/or harvest season. The results indicate that extraction media containing ethanol as main solvent achieved discrimination of self-shaded versus sun-exposed plants and harvest season of Annona muricata. Also, D-UPLS analysis allowed taxonomic discrimination between Annona muricata and Rollinia mucosa extract samples.es
dc.description.filFil: Afonso, Sabrina. Universidade Estadual de Londrina. Departamento de Química. Laboratório de Quimiometria em Ciências Naturais; Brasil.
dc.description.filFil: Pisano, Pablo Luis. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Analítica; Argentina.es
dc.description.filFil: Silva, Fabiano. Universidade Estadual de Londrina. Departamento de Química. Laboratório de Quimiometria em Ciências Naturais; Brasil.
dc.description.filFil: Scaminio, Ieda. Universidade Estadual de Londrina. Departamento de Química. Laboratório de Quimiometria em Ciências Naturais; Brasil.
dc.description.filFil: Olivieri, Alejandro César. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Departamento de Química Analítica; Argentina.es
dc.description.sponsorshipConselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)es
dc.description.sponsorshipFundação Araucáriaes
dc.description.sponsorshipUniversidad Nacional de Rosario (Argentina)es
dc.description.sponsorshipConsejo Nacional de Investigaciones Científicas y Técnicas (CONICET)es
dc.formatapplication/pdf
dc.format.extent2241-2248
dc.identifier.issn1678-4790
dc.identifier.urihttp://hdl.handle.net/2133/13920
dc.language.isoenges
dc.publisherBrazilian Chemical Societyes
dc.relation.publisherversionhttp://dx.doi.org/10.5935/0103-5053.20150210es
dc.relation.publisherversionhttp://jbcs.sbq.org.br/imagebank/pdf/v26n11a10.pdfes
dc.rightsopenAccesses
dc.rights.holderAfonso, Sabrinaes
dc.rights.holderPisano, Pablo Luises
dc.rights.holderSilva, Fabianoes
dc.rights.holderScaminio, Iedaes
dc.rights.holderOlivieri, Alejandro Césares
dc.rights.textAtribución 4.0 Internacional (CC BY 4.0)es
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/deed.es*
dc.subjectAnnona muricataes
dc.subjectRollinia mucosaes
dc.subjectHigh-performance liquid chromatographydiode array detectiones
dc.subjectMultivariate curve resolution-alternating least-squareses
dc.subjectDiscriminant-unfolded partial least-squareses
dc.titleDiscrimination of Annona muricata and Rollinia mucosa extracts by using multivariate curve resolution and partial least-squares regression of liquid chromatography-diode array dataes

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