A convenient and eco-friendly cerium(III) chloride-catalysed synthesis of methoxime derivatives of aromatic aldehydes and ketones
| dc.citation.title | Royal Society Open Science | es |
| dc.creator | Cortés, Iván | |
| dc.creator | Kaufman, Teodoro Saúl | |
| dc.creator | Bracca, Andrea Beatriz Juana | |
| dc.date.accessioned | 2018-06-10T21:43:04Z | |
| dc.date.available | 2018-06-10T21:43:04Z | |
| dc.date.issued | 2018-05-23 | |
| dc.description | The use of CeCl3·7H2O as an efficient and eco-friendly promoter for the convenient synthesis of methoximes derived from aromatic aldehydes and ketones, is reported. The transformations entail the use of equimolar amounts of MeONH2·HCl and NaOAc in EtOH at 50°C, and no special precautions are needed with regard to the presence of oxygen. The scope and limitations of the transformation were studied and a reaction mechanism was proposed. | es |
| dc.description.fil | Fil: Cortés, Iván. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR-CONICET); Argentina. | es |
| dc.description.fil | Fil: Kaufman, Teodoro Saúl. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR-CONICET); Argentina. | es |
| dc.description.fil | Fil: Bracca, Andrea Beatriz Juana. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR-CONICET); Argentina. | es |
| dc.description.sponsorship | Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) | es |
| dc.format | application/pdf | |
| dc.format.extent | 180279 | es |
| dc.identifier.issn | 2054-5703 | es |
| dc.identifier.uri | http://hdl.handle.net/2133/11432 | |
| dc.language.iso | eng | es |
| dc.publisher | The Royal Society | es |
| dc.relation.publisherversion | http://rsos.royalsocietypublishing.org/content/5/5/180279#ack-1 | es |
| dc.relation.publisherversion | http://dx.doi.org/10.1098/rsos.180279 | es |
| dc.rights | openAccess | es |
| dc.rights.holder | The Royal Society of Chemistry | es |
| dc.rights.holder | Universidad Nacional de Rosario | es |
| dc.rights.holder | Cortés, Iván | es |
| dc.rights.holder | Kaufman, Teodoro Saúl | es |
| dc.rights.holder | Bracca, Andrea Beatriz Juana | es |
| dc.rights.text | Atribución 4.0 Internacional (CC BY 4.0) | es |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/deed.es | es |
| dc.subject | Methoximation | es |
| dc.subject | Eco-friendly transformation | es |
| dc.subject | Cerium(III) chloride-promoted reaction | es |
| dc.title | A convenient and eco-friendly cerium(III) chloride-catalysed synthesis of methoxime derivatives of aromatic aldehydes and ketones | es |
| dc.type | article | |
| dc.type | artículo | |
| dc.type | publishedVersion | |
| dc.type.collection | articulo | |
| dc.type.version | publishedVersion | es |
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