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Photocatalytic C-H functionalization of nitrogen heterocycles mediated by a redox active protecting group

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dc.citation.titleEuropean Journal of Organic Chemistryes
dc.creatorPizzio, Marianela G.
dc.creatorMata, Ernesto Gabino
dc.creatorDauban, Philippe
dc.creatorSaget, Tanguy
dc.date.accessioned2023-09-07T18:02:40Z
dc.date.available2023-09-07T18:02:40Z
dc.date.issued2023-08-31
dc.descriptionHerein, we report a photocatalytic strategy for the C−H functionalization of saturated azaheterocycles under mild conditions with only one equivalent of starting material. Our strategy is based on a redox active benzamide protecting group that is activated via a halogen-atom transfer (XAT) process to trigger the formation of an α-amino radical. This nucleophilic radical intermediate was then engaged in Giese additions and radical cross couplings to afford C−H alkylated and arylated products.es
dc.description.filFil: Pizzio, Marianela G. Université Paris Saclay. Institut de Chimie des Substances Naturelles; France.es
dc.description.filFil: Dauban, Philippe. Université Paris Saclay. Institut de Chimie des Substances Naturelles; France.es
dc.description.filFil: Saget, Tanguy. Université Paris Saclay. Institut de Chimie des Substances Naturelles; France.es
dc.description.filFil: Mata, Ernesto Gabino. Universidad Nacional de Rosario. Facultad de Ciencias Bioquímicas y Farmacéuticas. Instituto de Química Rosario (IQUIR-CONICET); Argentina.es
dc.description.sponsorshipFrench National Research Agency: ANR‐21‐CE07‐0016‐01
dc.description.sponsorshipConsejo Nacional de Investigaciones Científicas y Técnicas (CONICET)
dc.description.sponsorshipMinisterio de Educación de Argentina
dc.formatapplication/pdf
dc.format.extent1-5es
dc.identifier.issn1434-193Xes
dc.identifier.urihttp://hdl.handle.net/2133/26259
dc.language.isoenges
dc.publisherJohn Wiley and Sons Inces
dc.relation.publisherversionhttps://doi.org/10.1002/ejoc.202300616
dc.relation.publisherversionhttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.202300616
dc.rightsopenAccesses
dc.rights.holderPizzio, Marianela G.es
dc.rights.holderMata, Ernesto Gabinoes
dc.rights.holderDauban, Philippees
dc.rights.holderSaget, Tanguyes
dc.rights.textAttribution 4.0 International (CC BY 4.0)es
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/*
dc.subjectAzaheterocycleses
dc.subjectC−H functionalizationes
dc.subjectHalogen atom transferes
dc.subjectHydrogen atom transferes
dc.subjectPhotoredox catalysises
dc.titlePhotocatalytic C-H functionalization of nitrogen heterocycles mediated by a redox active protecting groupes
dc.typearticle
dc.typeartículo
dc.typepublishedVersion
dc.type.collectionarticulo
dc.type.versionpublishedVersiones

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